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Le Chatelier's Chamber

About this simulation

Le Chatelier's Chamber is an interactive 3D gas-phase equilibrium simulation designed for chemistry classrooms. Inside a sealed glass cylinder with a draggable top piston and a heated base jacket, 36 colliding gas molecules continuously interconvert between reactants and products. Students can test the endothermic dinitrogen tetroxide dissociation (N2O4 ⇌ 2 NO2, where colourless cyan dimers split into reddish-brown monomers) or the exothermic Haber ammonia synthesis (N2 + 3 H2 ⇌ 2 NH3). Dragging the piston changes volume and pressure immediately, while adjusting temperature changes the equilibrium constant Kc, letting students watch forward and reverse rates rebalance until Q equals Kc.

What students can explore

  • In the N2O4 ⇌ 2 NO2 system, raise the Temperature slider toward 450 K and watch the gas mixture darken as endothermic dissociation shifts right toward brown NO2.
  • Drag the top piston downward to compress the chamber volume from 5.0 L to 1.8 L and watch N2O4 dimers reform as equilibrium shifts toward fewer moles of gas.
  • Switch System to N2 + 3 H2 ⇌ 2 NH3 (Exothermic) and compress the piston to see why high pressure favours ammonia production in the Haber process.
  • Lower the temperature in the Haber system and observe how an exothermic reaction shifts toward products (higher Kc) when cooled.
  • Click the Inject Reactant button or click molecules inside the cylinder to drop Q below Kc and watch the forward reaction surge until equilibrium is restored.

Learning objectives

  1. 1Use Le Chatelier's principle to predict how a reversible gas reaction responds to changes in concentration, pressure/volume, and temperature.
  2. 2Explain why compressing a gas mixture shifts equilibrium toward the side with fewer moles of gas molecules.
  3. 3Distinguish between disturbances that change the reaction quotient Q (volume or concentration) and temperature changes that alter Kc itself.
  4. 4Relate the macroscopic colour change of the N2O4 / NO2 gas mixture to the microscopic ratio of dimers to monomers.

Questions teachers ask

What does Le Chatelier's principle state?

Le Chatelier's principle states that when a chemical system at dynamic equilibrium experiences a change in temperature, pressure, volume, or concentration, the system shifts its equilibrium position in the direction that partially counteracts the imposed change.

Why does compressing the piston turn the N2O4 / NO2 gas paler?

In the reaction N2O4(g) ⇌ 2 NO2(g), one mole of pale N2O4 gas produces two moles of reddish-brown NO2 gas. Compressing the piston increases total pressure, so the system shifts left toward the side with fewer gas moles (N2O4), reducing brown NO2 concentration.

Does changing volume or pressure change the equilibrium constant Kc?

No. Changing volume or adding reactants alters the instantaneous reaction quotient Q, causing a net shift until Q returns to the same Kc value. Only a change in temperature alters the value of the equilibrium constant Kc.

Why does heating affect endothermic and exothermic reactions differently?

In an endothermic reaction (positive ΔH), thermal energy acts like a reactant, so raising temperature increases Kc and shifts equilibrium toward products. In an exothermic reaction (negative ΔH), heat is released as a product, so raising temperature decreases Kc and shifts equilibrium back toward reactants.

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